Please use this identifier to cite or link to this item:https://hdl.handle.net/20.500.12259/105433
Type of publication: Straipsnis Clarivate Analytics Web of Science ar/ir Scopus / Article in Clarivate Analytics Web of Science or / and Scopus (S1)
Field of Science: Aplinkos inžinerija / Environmental engineering (T004)
Author(s): Šantaraitė, Miglė;Sendžikienė, Eglė;Makarevičienė, Violeta;Kazancev, Kiril
Title: Biodiesel production by lipase-catalyzed in situ transesterification of rapeseed oil containing a high free fatty acid content with ethanol in iesel fuel media
Is part of: Energies. Basel : MDPI AG, 2020, vol. 13, iss.10
Extent: p. 1-12
Date: 2020
Keywords: Biodiesel;Ethanol;In situ transesterification;Lipase;Mineral diesel;Rapeseed oil
Abstract: In this study, low-quality rapeseed was used as a raw material for biodiesel fuel production. The application of such seeds with an enzyme catalyst is a green approach to producing renewable biodiesel fuel. During the in situ transesterification process, mineral diesel was selected as an extraction solvent for the simultaneous extraction and transesterification of rapeseed oil (RO). This allowed, at the end of the process, for the production of a mixture of mineral diesel and biodiesel fuel. Energy is saved using this process, as the need to extract the oil separately is eliminated and extraction and transesterification take place together in the in situ process. In this study, 11 different lipases were analyzed from which to select the most effective biocatalyst according to the chosen experimental conditions. The most suitable lipase for in situ transesterification was Lipozyme TL IM (Thermomyces lanuginosus). The impact of the temperature and duration of the reaction was investigated along with the concentration of the lipase. A ethanol-to-oil molar ratio of 5:1 was chosen. The optimal reaction conditions were as follows: a reaction duration of 7 h, a reaction temperature of 30 ◦C and a lipase concentration of 5% (based on oil weight). Under these conditions, 99.92% of oil was extracted from the rapeseed. The degree of oil transesterification acquired was 99.89%. A mineral diesel and rapeseed oil ethyl ester blend of 9:1 (w/w) was produced
Internet: https://www.mdpi.com/1996-1073/13/10/2588
https://doi.org/10.3390/en13102588
Affiliation(s): Miškų ir ekologijos fakultetas
Proj. "Vilko ekologijos tyrimai"
Vytauto Didžiojo universitetas
Žemės ūkio akademija
Appears in Collections:Universiteto mokslo publikacijos / University Research Publications

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